1. Product Scientific Research and Structural Stability
1.1 Crystal Chemistry and Bonding Characteristics
(Silicon Carbide Crucibles)
Silicon carbide (SiC) is a covalent ceramic composed of silicon and carbon atoms prepared in a tetrahedral latticework, primarily in hexagonal (4H, 6H) or cubic (3C) polytypes, each displaying outstanding atomic bond stamina.
The Si– C bond, with a bond energy of about 318 kJ/mol, is amongst the toughest in structural porcelains, providing exceptional thermal security, hardness, and resistance to chemical strike.
This robust covalent network causes a product with a melting point exceeding 2700 ° C(sublimes), making it one of the most refractory non-oxide porcelains offered for high-temperature applications.
Unlike oxide porcelains such as alumina, SiC preserves mechanical toughness and creep resistance at temperature levels above 1400 ° C, where several metals and traditional porcelains start to soften or deteriorate.
Its reduced coefficient of thermal development (~ 4.0 × 10 â»â¶/ K) integrated with high thermal conductivity (80– 120 W/(m · K)) allows fast thermal cycling without disastrous breaking, a crucial quality for crucible efficiency.
These innate homes come from the well balanced electronegativity and similar atomic sizes of silicon and carbon, which advertise a very secure and largely loaded crystal structure.
1.2 Microstructure and Mechanical Resilience
Silicon carbide crucibles are commonly made from sintered or reaction-bonded SiC powders, with microstructure playing a decisive role in durability and thermal shock resistance.
Sintered SiC crucibles are created via solid-state or liquid-phase sintering at temperatures over 2000 ° C, usually with boron or carbon ingredients to boost densification and grain boundary communication.
This process produces a fully dense, fine-grained structure with marginal porosity (
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