Production and Applications of Naphthalene Sulfonate Water Reducing Agent
Australian alumina ban disrupts Rusal Water Reducing Agent prices for chemicals. Patel said. "One possible outcome could be Chinese buyers buying alumina and reselling it through eastern Russian ports." Rusal has a 20% stake in the Queensland Alumina Refinery, which has a capacity of 3.95 million tonnes a year, thus providing Rusal with 790,000 tonnes a year, Patel said. In addition, Rusal's Nikolaev refinery in Ukraine, which has an annual capacity of 1.75 million tonnes, has been suspended due to the conflict, he added. WoodMac said Rusal was also experiencing supply chain problems at its 2 million tonne a year Aughinish refinery in Ireland.
Introduction to Naphthalene Sulfonate Water Reducing Agent:
It is the product of naphthalene sulfonated by sulfuric acid and then condensed with formaldehyde, which belongs to an anionic surfactant. The appearance of this kind of water-reducing agent depending on different products is light yellow to dark brown powder. It is soluble in water and has a good dispersing effect on many powder materials such as cement. The water reduction rate is 25%.
Preparation method of Naphthalene Sulfonate Water Reducing Agent:
The synthetic route of naphthalene sulfonate superplasticizer is as follows:
naphthalene → sulfonation → hydrolysis → condensation → neutralization → filtration → drying → product
The raw material for production is naphthalene. First, the sulfonation reaction is carried out with concentrated sulfuric acid. The mole ratio of naphthalene to sulfuric acid is 1:1.3-1.4. The reaction temperature was 160 - 165℃ and the reaction time was 3h. Then the reactants were cooled to 120℃ for hydrolysis. At this time, naphthalene sulfonic acid was stable, while naphthalene sulfonic acid was easy to hydrolyze, thus reducing the amount of naphthalene sulfonic acid to facilitate the next polycondensation reaction. The hydrolysis time was about 30min. The condensation reaction is an important reaction in the production of a naphthalene sulfonate water reducer. At a certain temperature, the sulfonated naphthalene was condensed with formaldehyde to form a polymer compound. This reaction strongly affects the performance of the product. In order to find the optimal process parameters, the effects of condensation time, condensation temperature, and the ratio of formaldehyde and naphthalene on product properties were investigated by means of uniform design. The optimal temperature condition is 104℃. The optimal reaction time was 6h. The optimal condition of formaldehyde dosage is 0.75. The maximum expected theoretical value is 18.3.
Industrial production process of Naphthalene Sulfonate Water Reducing Agent:
(1) naphthalene: Naphthalene is solid at room temperature, and it is necessary to put naphthalene into the naphthalene kettle for heating and melting.
(2) sulfonation: The sulfonation process is to add concentrated sulfuric acid to the sulfonation kettle and react with it to produce naphthalene sulfonic acid. There are two types of naphthalene sulfonic acid: α -naphthalene sulfonic acid and β -naphthalene sulfonic acid.
(3) hydrolysis: As α -naphthalene sulfonic acid is produced in the sulfonation reaction, its presence is not conducive to the condensation reaction, so it needs to add water to hydrolyze α -naphthalene sulfonic acid.
(4) condensation: After the end of hydrolysis reaction to condensation kettle drop formaldehyde, and β -naphthalene sulfonic acid reaction to generate naphthalene sulfonated formaldehyde condensation.
(5) neutralization: After condensation, the material enters the neutralization kettle, drops liquid alkali, neutralizes the excess sulfuric acid in the sulfonation reaction, and stops dropping when the PH reaches 7-9.
The control system mainly monitors the production status of four different reaction reactors and their batching tanks. The production line can also carry out four production lines at the same time. Taking production line A as an example, there are one naphthalene reactor, two sulfonation reactors, four condensation reactors, and one neutralization reactor. Each reaction kettle has a feed valve, discharge valve, emptying valve, hot oil valve, cooling water valve, steam pressure valve, flush valve, etc., the reaction kettle with a raw material tank, two sulfonated kettles shared a sulfuric acid tank, every two condensation kettles would be equipped with a set of formaldehyde tank and dilution tank, each condensation kettle has a hydrolysis tank, liquid alkali tank to neutralize the alkali added drops in the kettle.
Applications of Naphthalene Sulfonate Water Reducing Agent:
Naphthalene water-reducing agent is a kind of concrete additive invented by Dr. Hwab Kenichi in Japan in 1962. It is a kind of chemical synthetic product of naphthalene sulfonate formaldehyde condensation, with industrial naphthalene, concentrated sulfuric acid, formaldehyde, and alkali as the main raw material. Adding a naphthalene water-reducing agent to concrete can not only improve the strength of concrete but also improve its various properties, such as wear resistance, corrosion resistance, permeability resistance, etc. Therefore, naphthalene water-reducing agent is widely used in roads, bridges, tunnels, docks, civil buildings, and other industries.
Suppliers of Concrete Additives
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The COVID-19 pandemic has affected economies and chemical companies in many countries around the world. Measures such as extending holidays and resuming work were taken to control the development of the epidemic, and the normal operation of some chemical enterprises was also affected to some extent.
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