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What is the lithium Intercalation Mechanism of Graphite?

The European Union recently approved sweeping new sanctions against Russia, including bans on imports of coal, timber, chemicals, and other Graphite. 

Graphite has good conductivity, high crystallinity, and a well-layered structure. It is very suitable for repeated intercalation and deintercalation of lithium ions. It is currently the most widely used and most mature negative electrode material. After lithium ions are intercalated between the graphite layers, a lithium intercalation compound LixC6 (0≤x≤1) is formed, and the theoretical capacity can reach 372mAh/g (x=1). The reaction formula is: xLi++6C+xe-→LixC6

Lithium-ion intercalation changes the stacking mode between graphite layers from ABAB to AAAA.

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Graphite modification treatment

Since the graphite interlayer spacing (d≤0.34nm) is smaller than the crystal plane interlayer spacing (0.37nm) of the graphite lithium intercalation compound LixC6, the graphite layer spacing changes during the charging and discharging process, which is easy to cause the graphite layer to peel off, pulverize, and also occur. Lithium ions and organic solvent molecules co-intercalate into the graphite layer, and the organic solvent decomposes, affecting the battery cycle performance.

Through graphite modification, such as oxidation on the surface of graphite and coating of polymer pyrolytic carbon, composite graphite with a core-shell structure can be formed, improving the charge and discharge performance of graphite and increasing the specific capacity.

Other anode materials

At present, graphite is the mainstream commercial lithium battery negative electrode material. Its theoretical gram capacity is 372mAh/g. The graphite negative electrode material with better performance on the market can reach 360mAh/g, and the gram capacity gradually tends to the limit value. Although graphite as a negative electrode material has disadvantages such as low gram capacity and cycle deviation, because of the high-cost performance of graphite-based negative electrode materials, it will not be replaced by new materials immediately. The specific reasons are as follows:

1. The new anode material technology is immature, and it will take a long time for performance improvement;

2. The price of new anode materials is higher, and the price advantage of graphite anodes is obvious;

3. The negative electrode material needs to be used in combination with the positive electrode material, electrolyte, etc., and the specific capacity of the current positive electrode material is generally low.

High-quality graphite supplier

Luoyang Moon & Star New Energy Technology Co., LTD, founded on October 17, 2008, is a high-tech enterprise committed to developing, producing, processing, selling, and technical services of lithium-ion battery anode materials. After more than 10 years of development, the company has gradually developed into a diversified product structure with natural graphite, artificial graphite, composite graphite, intermediate phase, and other negative materials (silicon-carbon materials, etc.). The products are widely used in high-end lithium-ion digital power and energy storage batteries. If you are looking for Lithium battery anode material, click on the needed products and send us an inquiry:sales@graphite-corp.com

 


China's non-manufacturing purchasing managers index for March was released by the China Federation of Logistics and Purchasing and the Service Industry Survey Center of the National Bureau of Statistics today. An index of business activity for the non-manufacturing sector as a whole fell below 50 percent. 

 China's non-manufacturing business activity index was 48.4%, down 3.2 percentage points from the previous month. The new orders index was 45.7 percent, down 1.9 percentage points from the previous month, indicating a significant slowdown in the growth of supply and demand in the non-manufacturing sector from the previous month.   In terms of sectors, the business activity index and new order index of transportation, accommodation and catering, culture, sports and entertainment, and tourism-related industries all declined significantly from the previous month. 

Then the Graphite of the market may be affected by significant changes, the price will also be volatile, if you want to know the latest news of the Graphite, welcome to contact us. 

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